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The red cat and an ox mnemonics are useful to remember the same. Red cat: Reduction at cathode; An ox: Anode for oxidation. [32] PANIC : Positive Anode, Negative Is Cathode; The words oxidation and anode, both begin with vowels. Also, both reduction and cathode begin with consonants. [29] Fat Cat: electrons flow From Anode To Cathode
The energy efficiency of a process involving chemical change may be expressed relative to these theoretical minima or maxima.The difference between the change of enthalpy and the change of Gibbs energy of a chemical transformation at a particular temperature indicates the heat input required or the heat removal (cooling) required to maintain ...
The above efficiency formulas are based on simple idealized mathematical models of engines, with no friction and working fluids that obey simple thermodynamic rules called the ideal gas law. Real engines have many departures from ideal behavior that waste energy, reducing actual efficiencies below the theoretical values given above.
The maximum efficiency (i.e., the Carnot heat engine efficiency) of a heat engine operating between hot and cold reservoirs, denoted as H and C respectively, is the ratio of the temperature difference between the reservoirs to the hot reservoir temperature, expressed in the equation
The thermodynamic square can also be used to find the first-order derivatives in the common Maxwell relations.The following procedure should be considered: Looking at the four corners of the square and make a shape with the quantities of interest.
N i is the number of particles (or number of moles) composing the ith chemical component. This is one form of the Gibbs fundamental equation. [10] In the infinitesimal expression, the term involving the chemical potential accounts for changes in Gibbs free energy resulting from an influx or outflux of particles.
Atom economy. Atom economy (atom efficiency/percentage) is the conversion efficiency of a chemical process in terms of all atoms involved and the desired products produced. The simplest definition was introduced by Barry Trost in 1991 and is equal to the ratio between the mass of desired product to the total mass of reactants, expressed as a percentage.
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.