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The red cat and an ox mnemonics are useful to remember the same. Red cat: Reduction at cathode; An ox: Anode for oxidation. [32] PANIC : Positive Anode, Negative Is Cathode; The words oxidation and anode, both begin with vowels. Also, both reduction and cathode begin with consonants. [29] Fat Cat: electrons flow From Anode To Cathode
The energy efficiency of a process involving chemical change may be expressed relative to these theoretical minima or maxima.The difference between the change of enthalpy and the change of Gibbs energy of a chemical transformation at a particular temperature indicates the heat input required or the heat removal (cooling) required to maintain ...
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
The thermodynamic square can also be used to find the first-order derivatives in the common Maxwell relations.The following procedure should be considered: Looking at the four corners of the square and make a shape with the quantities of interest.
Ligand efficiency is a measurement of the binding energy per atom of a ligand to its binding partner, such as a receptor or enzyme. [ 1 ] Ligand efficiency is used in drug discovery research programs to assist in narrowing focus to lead compounds with optimal combinations of physicochemical properties and pharmacological properties.
The maximum efficiency (i.e., the Carnot heat engine efficiency) of a heat engine operating between hot and cold reservoirs, denoted as H and C respectively, is the ratio of the temperature difference between the reservoirs to the hot reservoir temperature, expressed in the equation
A metric similar to reaction mass efficiency is the effective mass efficiency, as suggested by Hudlicky et al. [9] It is defined as the percentage of the mass of the desired product relative to the mass of all non-benign reagents used in its synthesis. The reagents here may include any used reactant, solvent or catalyst.
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.