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Polarizability increases down on columns of the periodic table. [9] Likewise, larger molecules are generally more polarizable than smaller ones. Water is a very polar molecule, but alkanes and other hydrophobic molecules are more polarizable. Water with its permanent dipole is less likely to change shape due to an external electric field.
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter ε , is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy ...
The correlation should, however, be treated with caution. For instance, dichloromethane has a value of ε r of 9.08 (20 °C) and is rather poorly soluble in water (13 g/L or 9.8 mL/L at 20 °C); at the same time, tetrahydrofuran has its ε r = 7.52 at 22 °C, but it is completely miscible with water
The polarizability of individual particles in the medium can be related to the average susceptibility and polarization density by the Clausius–Mossotti relation. In general, the susceptibility is a function of the frequency ω of the applied field.
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In many materials the polarizability starts to saturate at high values of electric field. This saturation can be modelled by a nonlinear susceptibility . These susceptibilities are important in nonlinear optics and lead to effects such as second-harmonic generation (such as used to convert infrared light into visible light, in green laser ...
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