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Depiction of a hydrogen atom showing the diameter as about twice the Bohr model radius. (Image not to scale) A hydrogen atom is an atom of the chemical element hydrogen.The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb force.
In chemistry, the whole number rule states that the masses of the isotopes are whole number multiples of the mass of the hydrogen atom. [1] The rule is a modified version of Prout's hypothesis proposed in 1815, to the effect that atomic weights are multiples of the weight of the hydrogen atom. [ 2 ]
Atomic units are chosen to reflect the properties of electrons in atoms, which is particularly clear in the classical Bohr model of the hydrogen atom for the bound electron in its ground state: Mass = 1 a.u. of mass; Charge = −1 a.u. of charge; Orbital radius = 1 a.u. of length; Orbital velocity = 1 a.u. of velocity [44]: 597
According to the whole number rule proposed by Francis Aston, the mass of an isotope is roughly, but not exactly, its mass number A (Z + N) times an atomic mass unit (u), plus or minus binding energy discrepancy – atomic mass unit being the modern approximation for "mass of a proton, neutron, or hydrogen atom".
Hydrogen, as atomic H, is the most abundant chemical element in the universe, making up 75% of normal matter by mass and >90% by number of atoms. [96] In astrophysics, neutral hydrogen in the interstellar medium is called H I and ionized hydrogen is called H II . [ 97 ]
For other isotopes, the isotopic mass is usually within 0.1 u of the mass number. For example, 35 Cl (17 protons and 18 neutrons) has a mass number of 35 and an isotopic mass of 34.96885. [7] The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess, [8] which for 35 Cl is –0.03115.
The last expression in the first equation shows that the wavelength of light needed to ionize a hydrogen atom is 4π/α times the Bohr radius of the atom. The second equation is relevant because its value is the coefficient for the energy of the atomic orbitals of a hydrogen atom: E n = − h c R ∞ / n 2 {\displaystyle E_{n}=-hcR_{\infty }/n ...
In 1803 John Dalton proposed to use the (still unknown) atomic mass of the lightest atom, hydrogen, as the natural unit of atomic mass. This was the basis of the atomic weight scale. [12] For technical reasons, in 1898, chemist Wilhelm Ostwald and others proposed to redefine the unit of atomic mass as 1 / 16 the mass of an oxygen atom. [13]