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The electrochemical equivalent of a substance is the mass of the substance deposited to one of the electrodes when a current of 1 ampere is passed for 1 second, i.e. a quantity of electricity of one coulomb is passed. The formula for finding electrochemical equivalent is as follows: = /
Michael Faraday reported that the mass (m) of a substance deposited or liberated at an electrode is directly proportional to the charge (Q, for which the SI unit is the ampere-second or coulomb). [ 3 ] m ∝ Q m Q = Z {\displaystyle m\propto Q\quad \implies \quad {\frac {m}{Q}}=Z}
The mass-to-charge ratio (m/Q) is a physical quantity relating the mass (quantity of matter) and the electric charge of a given particle, expressed in units of kilograms per coulomb (kg/C). It is most widely used in the electrodynamics of charged particles , e.g. in electron optics and ion optics .
As the electroactive molecules are consumed, the current also decreases, approaching zero when the conversion is complete. The sample mass, molecular mass, number of electrons in the electrode reaction, and number of electrons passed during the experiment are all related by Faraday's laws. It follows that, if three of the values are known, then ...
In particle physics, the electron mass (symbol: m e) is the mass of a stationary electron, also known as the invariant mass of the electron. It is one of the fundamental constants of physics . It has a value of about 9.109 × 10 −31 kilograms or about 5.486 × 10 −4 daltons , which has an energy-equivalent of about 8.187 × 10 −14 joules ...
In the SI system of units, the value of the elementary charge is exactly defined as = 1.602 176 634 × 10 −19 coulombs, or 160.2176634 zeptocoulombs (zC). [3] Since the 2019 revision of the SI, the seven SI base units are defined in terms of seven fundamental physical constants, of which the elementary charge is one.
The equivalent weight of an element is the mass which combines with or displaces 1.008 gram of hydrogen or 8.0 grams of oxygen or 35.5 grams of chlorine. The equivalent weight of an element is the mass of a mole of the element divided by the element's valence. That is, in grams, the atomic weight of the element divided by the usual valence. [2]
Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called percentage by weight, abbreviated wt.% or % w/w; see mass versus weight). It is one way of expressing the composition of a mixture in a dimensionless size ; mole fraction (percentage by moles , mol%) and volume fraction ...