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They further fine-tuned the film's composite dynamics, leading to high-efficiency quasi-2D perovskite green LEDs with an effective area of 9.0 cm 2. An external quantum efficiency (EQE) of 16.4% was attained at <n> = 3, making it the most efficient large-area perovskite LED. Moreover, a luminance of 9.1×104 cd/m 2 was achieved in the <n> = 10 ...
Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
As the length of the 2D organic ion increases, the spacing between the corner sharing octahedra does as well, forming a 2D or quasi-2D structure. [30] The organic and inorganic layers are held together by van der waals forces. A formula of R 2 A n−1 B n X 3n+1 is used to characterize the 2D and quasi 2D structures. [30]
Ruddlesden-Popper (RP) phases are a type of perovskite structure that consists of two-dimensional perovskite-like slabs interleaved with cations.The general formula of an RP phase is A n+1 B n X 3n+1, where A and B are cations, X is an anion (e.g., oxygen), and n is the number of octahedral layers in the perovskite-like stack. [1]
MgCNi 3 is a metallic perovskite compound and has received lot of attention because of its superconducting properties. An even more exotic type of perovskite is represented by the mixed oxide-aurides of Cs and Rb, such as Cs 3 AuO, which contain large alkali cations in the traditional "anion" sites, bonded to O 2− and Au − anions. [citation ...
Perovskite MAPbX 3 thin films have been shown to be promising materials for optical gain applications such as lasers and optical amplifiers. [137] [138] Afterwards, the lasing properties of colloidal perovskite NCs such as CsPbX 3 nanocubes, [19] [139] MAPbBr 3 nanoplatelets [113] and FAPbX 3 nanocubes [83] [82] were also demonstrated.
Similar-to-graphene properties are sought for in silicene, phosphorene, boron nitride, zinc oxide, gallium nitride, as well as in 2D transition metal dichalkogenides and oxides, plus a number of other organic and inorganic 2D and quasi-2D compounds with expected similar properties. One of the main important features of these systems is their ...
A polaron is a quasiparticle used in condensed matter physics to understand the interactions between electrons and atoms in a solid material. The polaron concept was proposed by Lev Landau in 1933 [1] and Solomon Pekar in 1946 [2] to describe an electron moving in a dielectric crystal where the atoms displace from their equilibrium positions to effectively screen the charge of an electron ...