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  2. Knorr pyrrole synthesis - Wikipedia

    en.wikipedia.org/wiki/Knorr_pyrrole_synthesis

    Levi and Zanetti extended the Knorr synthesis in 1894 to the use of acetylacetone (2,4-pentanedione) in reaction with ethyl 2-oximinoacetoacetate. The result was ethyl 4-acetyl-3,5-dimethylpyrrole-2-carboxylate, where "OEt" = R 1 = R 3 = Me, and R 2 = COOEt. [9] The 4-acetyl group could easily be converted to a 4-ethyl group by Wolff-Kishner ...

  3. Pentanedione - Wikipedia

    en.wikipedia.org/wiki/Pentanedione

    Acetylacetone (2,4-pentanedione) Acetylpropionyl (2,3-pentanedione) See also. C 5 H 8 O 2; Cyclopentanedione This page was last edited on 15 March ...

  4. 5.11 Tactical - Wikipedia

    en.wikipedia.org/wiki/5.11_Tactical

    Costa bought the entire company in 2002 and ended up selling Royal Robbins Clothing back to Robbins in 2003, but kept the 5.11 brand and spun off a whole new company called 511 Inc. or 5.11 Tactical. Partnering with the FBI , Dan Costa and his co-partner Francisco Morales began creating additional tactical apparel and improving on the existing ...

  5. Acetylpropionyl - Wikipedia

    en.wikipedia.org/wiki/Acetylpropionyl

    Acetylpropionyl, also known as acetyl propionyl or 2,3-pentanedione, [1] is an organic compound, specifically a diketone. [2] Uses for acetylpropionyl include as a: Solvent for cellulose acetate, paints, inks, and lacquers; Starting material for dyes, pesticides, and drugs

  6. Enol - Wikipedia

    en.wikipedia.org/wiki/Enol

    If R 1 and R 2 (note equation at top of page) are different substituents, there is a new stereocenter formed at the alpha position when an enol converts to its keto form. Depending on the nature of the three R groups, the resulting products in this situation would be diastereomers or enantiomers .

  7. Acetylacetone - Wikipedia

    en.wikipedia.org/wiki/Acetylacetone

    It forms the acetylacetonate anion C 5 H 7 O − 2 (commonly abbreviated acac −): C 5 H 8 O 2 ⇌ C 5 H 7 O − 2 + H + The structure of the acetylacetonate anion (acac −) In the acetylacetonate anion, both C-O bonds are equivalent. Both C-C central bonds are equivalent as well, with one hydrogen atom bonded to the central carbon atom (the ...

  8. Guanidine - Wikipedia

    en.wikipedia.org/wiki/Guanidine

    As a result, its pK aH is 13.6 [2] (pK b of 0.4) meaning that guanidine is a very strong base in water; in neutral water, it exists almost exclusively as guanidinium. Due to this, most guanidine derivatives are salts containing the conjugate acid.

  9. Category:Guanidines - Wikipedia

    en.wikipedia.org/wiki/Category:Guanidines

    Guanidine; 5'-Guanidinonaltrindole; ... This page was last edited on 11 January ... (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 ...