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  2. Valeric acid - Wikipedia

    en.wikipedia.org/wiki/Valeric_acid

    The valerate, or pentanoate, ion is C 4 H 9 COO −, the conjugate base of valeric acid. It is the form found in biological systems at physiological pH . A valerate, or pentanoate, compound is a carboxylate salt or ester of valeric acid.

  3. Isomerization - Wikipedia

    en.wikipedia.org/wiki/Isomerization

    The compound with the formula (C 5 H 5) 2 Fe 2 (CO) 4 exists as three isomers in solution. In one isomer the CO ligands are terminal. When a pair of CO are bridging, cis and trans isomers are possible depending on the location of the C 5 H 5 groups. [7] Another example in organometallic chemistry is the linkage isomerization of ...

  4. Neighbouring group participation - Wikipedia

    en.wikipedia.org/wiki/Neighbouring_group...

    In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.

  5. List of esters - Wikipedia

    en.wikipedia.org/wiki/List_of_esters

    An ester of carboxylic acid.R stands for any group (organic or inorganic) and R′ stands for organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (−R).

  6. Pivalic acid - Wikipedia

    en.wikipedia.org/wiki/Pivalic_acid

    Pivalic acid is sometimes used as an internal chemical shift standard for NMR spectra of aqueous solutions. While DSS is more commonly used for this purpose, the minor peaks from protons on the three methylene bridges in DSS can be problematic. The 1 H NMR spectrum at 25 °C and neutral pH is a singlet at 1.08 ppm. [citation needed]

  7. Structural isomer - Wikipedia

    en.wikipedia.org/wiki/Structural_isomer

    In chemistry, a structural isomer (or constitutional isomer in the IUPAC nomenclature [1]) of a compound is another compound whose molecule has the same number of atoms of each element, but with logically distinct [clarification needed] bonds between them. [2] [3] The term metamer was formerly used for the same concept. [4]

  8. Isovaleric acid - Wikipedia

    en.wikipedia.org/wiki/Isovaleric_acid

    An isovalerate or 3-methylbutanoate ion is (CH 3) 2 CHCH 2 COO −, the conjugate base of the acid. It is the form found in biological systems at physiological pH . An isovalerate or 3-methylbutanoate compound is a salt or ester of the acid.

  9. IUPAC nomenclature of organic chemistry - Wikipedia

    en.wikipedia.org/wiki/IUPAC_nomenclature_of...

    For example, the three isomers of xylene CH 3 C 6 H 4 CH 3, commonly the ortho-, meta-, and para-forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4-dimethylbenzene. The cyclic structures can also be treated as functional groups themselves, in which case they take the prefix "cyclo alkyl -" (e.g. "cyclohexyl-") or for benzene, "phenyl-".