Search results
Results from the WOW.Com Content Network
Triphenylamine is an organic compound with formula (C 6 H 5) 3 N. In contrast to most amines, triphenylamine is nonbasic. At room temperature it appears as a colorless crystalline solid, with monoclinic structure. It is well miscible in diethyl ether and benzene, but it is practically insoluble in water, and partially in ethanol.
In the reaction, thermal or photochemical decomposition of N-halogenated amine 1 in the presence of a strong acid (concentrated sulfuric acid or concentrated CF 3 CO 2 H) generates a nitrogen radical intermediate. The radical then abstracts an intramolecular hydrogen atom to give a cyclic amine 2 (pyrrolidine or, in some cases, piperidine).
The reaction mechanism of the Mitsunobu reaction is fairly complex. The identity of intermediates and the roles they play has been the subject of debate. Initially, the triphenyl phosphine (2) makes a nucleophilic attack upon diethyl azodicarboxylate (1) producing a betaine intermediate 3, which deprotonates the carboxylic acid (4) to form the ion pair 5.
Diphenylamine is an organic compound with the formula (C 6 H 5) 2 NH. The compound is a derivative of aniline, consisting of an amine bound to two phenyl groups. The compound is a colorless solid, but commercial samples are often yellow due to oxidized impurities. [5]
One of several nitrogen oxides, nitrogen dioxide is a reddish-brown gas. It is a paramagnetic , bent molecule with C 2v point group symmetry . Industrially, NO 2 is an intermediate in the synthesis of nitric acid , millions of tons of which are produced each year, primarily for the production of fertilizers .
Triethylamine is commonly used in the production of anionic Polyurethane dispersions (resins dispersed in water rather than solvents) as a neutralizing agent.. Triethylamine is used to give salts of various carboxylic acid-containing pesticides, e.g. Triclopyr and 2,4-dichlorophenoxyacetic acid.
It contains a nitrogen-oxygen coordinate covalent bond with three additional hydrogen and/or substituent-groups attached to nitrogen. Sometimes it is written as R 3 N→O or, alternatively, [1] as R 3 N=O. In the strict sense, the term amine oxide applies only to oxides of tertiary amines. Sometimes it is also used for the analogous derivatives ...
The cheletropic reactions of 1,3-dienes with sulfur dioxide have been extensively investigated in terms of kinetics (see above for general reaction). In the first quantitative measurement of kinetic parameters for this reaction, a 1976 study by Isaacs and Laila measured the rates of addition of sulfur dioxide to butadiene derivatives.