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Effusion from an equilibrated container into outside vacuum can be calculated based on kinetic theory. [2] The number of atomic or molecular collisions with a wall of a container per unit area per unit time (impingement rate) is given by: =. assuming mean free path is much greater than pinhole diameter and the gas can be treated as an ideal gas.
Rate 1 is the rate of effusion for the first gas. (volume or number of moles per unit time). Rate 2 is the rate of effusion for the second gas. M 1 is the molar mass of gas 1 M 2 is the molar mass of gas 2. Graham's law states that the rate of diffusion or of effusion of a gas is inversely proportional to the square root of its molecular weight.
To calculate the velocity distribution of particles hitting this small area, we must take into account that all the particles with (,,) that hit the area within the time interval are contained in the tilted pipe with a height of and a volume of (); Therefore, compared to the Maxwell distribution, the velocity distribution will have an ...
In fluid mechanics, the pressure-gradient force is the force that results when there is a difference in pressure across a surface. In general, a pressure is a force per unit area across a surface. A difference in pressure across a surface then implies a difference in force, which can result in an acceleration according to Newton's second law of ...
The aerodynamic force is the resultant vector from adding the lift vector, perpendicular to the flow direction, and the drag vector, parallel to the flow direction. Forces on an aerofoil . In fluid mechanics , an aerodynamic force is a force exerted on a body by the air (or other gas ) in which the body is immersed, and is due to the relative ...
Molecular diffusion occurs in gases, liquids, and solids. Diffusion is a result of thermal motion of molecules. Usually, convection occurs as a result of the diffusion process. The rate at which diffusion occurs depends on the state of the molecules: it occurs at a high rate in gases, a slower rate in liquids, and an even slower rate in solids.
Pulmonary compliance is calculated using the following equation, where ΔV is the change in volume, and ΔP is the change in pleural pressure: = For example, if a patient inhales 500 mL of air from a spirometer with an intrapleural pressure before inspiration of −5 cm H 2 O and −10 cm H 2 O at the end of inspiration.
However, the equilibrium constant will no longer be dimensionless and will have units of reciprocal concentration instead. The difference between the kinetic and thermodynamic derivations of the Langmuir model is that the thermodynamic uses activities as a starting point while the kinetic derivation uses rates of reaction.