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The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
A formula to compute the ebullioscopic constant is: [2] = R is the ideal gas constant. M is the molar mass of the solvent. T b is boiling point of the pure solvent in kelvin. ΔH vap is the molar enthalpy of vaporization of the solvent.
Jurin's law, or capillary rise, is the simplest analysis of capillary action—the induced motion of liquids in small channels [1] —and states that the maximum height of a liquid in a capillary tube is inversely proportional to the tube's diameter.
The Helmholtz free energy is defined as [3], where . F is the Helmholtz free energy (sometimes also called A, particularly in the field of chemistry) (SI: joules, CGS: ergs),; U is the internal energy of the system (SI: joules, CGS: ergs),
This is due to the nature of right triangles. Additionally, from the equation for the range : = We can see that the range will be maximum when the value of is the highest (i.e. when it is equal to 1).
G = Gibbs free energy p = Pressure H = Enthalpy S = Entropy U = Internal energy V = Volume F = Helmholtz free energy T = Temperature. The thermodynamic square (also known as the thermodynamic wheel, Guggenheim scheme or Born square) is a mnemonic diagram attributed to Max Born and used to help determine
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