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This sodium hydroxide solution can be used to measure the equivalent weight of an unknown acid. For example, if it takes 13.20±0.03 cm 3 of the sodium hydroxide solution to neutralise 61.3±0.1 mg of an unknown acid, the equivalent weight of the acid is:
More accurate measurements become important in the large volumes used in commercial food production. Also, a home cook can use greater precision at times. Water at 4.0 °C (39.2 °F) may be volumetrically measured then weighed to determine an unknown measuring-utensil volume [13] without the need for a water-density adjustment. [14]
An equivalent (symbol: officially equiv; [1] unofficially but often Eq [2]) is the amount of a substance that reacts with (or is equivalent to) an arbitrary amount (typically one mole) of another substance in a given chemical reaction. It is an archaic quantity that was used in chemistry and the biological sciences (see Equivalent weight § In ...
V eq is the volume of titrant (ml) consumed by the crude oil sample and 1 ml of spiking solution at the equivalent point, b eq is the volume of titrant (ml) consumed by 1 ml of spiking solution at the equivalent point, 56.1 g/mol is the molecular weight of KOH, W oil is the mass of the sample in grams. The normality (N) of titrant is calculated as:
For example, in a recipe that calls for 10 pounds of flour and 5 pounds of water, the corresponding baker's percentages are 100% for the flour and 50% for the water. Because these percentages are stated with respect to the weight of flour rather than with respect to the weight of all ingredients, the sum of these percentages always exceeds 100%.
Normality can be used for acid-base titrations. For example, sulfuric acid (H 2 SO 4) is a diprotic acid. Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: f eq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be ...
Where HV is the hydroxyl value; V B is the amount (ml) potassium hydroxide solution required for the titration of the blank; V acet is the amount (ml) of potassium hydroxide solution required for the titration of the acetylated sample; W acet is the weight of the sample (in grams) used for acetylation; N is the normality of the titrant; 56.1 is ...
It can be prepared by treating a potassium-containing base such as potassium hydroxide or potassium carbonate with acetic acid: CH 3 COOH + KOH → CH 3 COOK + H 2 O. This sort of reaction is known as an acid-base neutralization reaction. At saturation, the sesquihydrate in water solution (CH 3 COOK·1½H 2 O) begins to form semihydrate at 41.3 ...