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Heat transfer is a process function (or path function), as opposed to functions of state; therefore, the amount of heat transferred in a thermodynamic process that changes the state of a system depends on how that process occurs, not only the net difference between the initial and final states of the process.
Phonon heat capacity c v,p (in solid c v,p = c p,p, c v,p : constant-volume heat capacity, c p,p: constant-pressure heat capacity) is the temperature derivatives of phonon energy for the Debye model (linear dispersion model), is [19], = | = / (=), where T D is the Debye temperature, m is atomic mass, and n is the atomic number density (number ...
Phase transitions play many important roles in biological systems. Examples include the lipid bilayer formation, the coil-globule transition in the process of protein folding and DNA melting, liquid crystal-like transitions in the process of DNA condensation, and cooperative ligand binding to DNA and proteins with the character of phase ...
Mass transfer in a system is governed by Fick's first law: 'Diffusion flux from higher concentration to lower concentration is proportional to the gradient of the concentration of the substance and the diffusivity of the substance in the medium.' Mass transfer can take place due to different driving forces. Some of them are: [12]
In general, matter in diffusive motion carries with it some internal energy, and some microscopic potential energy changes accompany the motion. An open system is not adiabatically enclosed. There are some cases in which a process for an open system can, for particular purposes, be considered as if it were for a closed system.
Such motion, in the presence of a temperature gradient, contributes to heat transfer. Because the molecules in aggregate retain their random motion, the total heat transfer is then due to the superposition of energy transport by random motion of the molecules and by the bulk motion of the fluid. It is customary to use the term convection when ...
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A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. [1]