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The temperature-entropy conjugate pair is concerned with the transfer of energy, especially for a closed system. An isothermal process occurs at a constant temperature. An example would be a closed system immersed in and thermally connected with a large constant-temperature bath. Energy gained by the system, through work done on it, is lost to ...
During a closed cycle, the system returns to its original thermodynamic state of temperature and pressure. Process quantities (or path quantities), such as heat and work are process dependent. For a cycle for which the system returns to its initial state the first law of thermodynamics applies:
In some cases, when analyzing a thermodynamic process, one can assume that each intermediate state in the process is at equilibrium. Such a process is called quasistatic. [4] For a process to be reversible, each step in the process must be reversible. For a step in a process to be reversible, the system must be in equilibrium throughout the step.
Such motion, in the presence of a temperature gradient, contributes to heat transfer. Because the molecules in aggregate retain their random motion, the total heat transfer is then due to the superposition of energy transport by random motion of the molecules and by the bulk motion of the fluid. It is customary to use the term convection when ...
A model of a four-phase Stirling cycle. Most thermodynamics textbooks describe a highly simplified form of Stirling cycle consisting of four processes. This is known as an "ideal Stirling cycle", because it is an "idealized" model, and not necessarily an optimized cycle.
Heat transfer is a process function (or path function), as opposed to functions of state; therefore, the amount of heat transferred in a thermodynamic process that changes the state of a system depends on how that process occurs, not only the net difference between the initial and final states of the process.
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Slack phonon conductivity model mainly considering acoustic phonon scattering (three-phonon interaction) is given as [27] [28] =, = /, / (>,, where M is the mean atomic weight of the atoms in the primitive cell, V a =1/n is the average volume per atom, T D,∞ is the high-temperature Debye temperature, T is the temperature, N o is the number of ...