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Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes as a solvate with ligands bound to Na +. [1]
Naphthalenesulfonates are derivatives of sulfonic acid which contain a naphthalene functional unit. A related family of compounds are the aminonaphthalenesulfonic acids.Of commercial importance are the alkylnaphthalene sulfonates, which are used as superplasticizers in concrete.
With alkali metals, naphthalene forms the dark blue-green radical anion salts such as sodium naphthalene, Na + C 10 H − 8. The naphthalene anions are strong reducing agents. Naphthalene can be hydrogenated under high pressure in the presence of metal catalysts to give 1,2,3,4-tetrahydronaphthalene(C 10 H 12), also known as tetralin.
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Aminonaphthalenesulfonic acids are compounds with the composition C 10 H 6 (NH 2)(SO 3 H), being derived from naphthalene (C 10 H 8) substituted by an amino and sulfonic acid groups. These compounds are colorless solids. They are useful precursors to dyes. [1]
Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. As a result, sodium usually forms ionic compounds involving the Na + cation. [1] Sodium is a reactive alkali metal and is much more stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds.
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With alkali metals, 1-methylnaphthalene forms radical anion salts such as sodium 1-methylnaphthalene. Compared to its structural analog sodium naphthalene, sodium 1-methylnaphthalene is more soluble, which is useful for low-temperature reductions. [4]