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Copper(I) iodide is an inorganic compound with the chemical formula Cu I. It is also known as cuprous iodide . It is useful in a variety of applications ranging from organic synthesis to cloud seeding .
Copper is a chemical element with the symbol Cu (from Latin: cuprum) and the atomic number of 29. It is easily recognisable, due to its distinct red-orange color . Copper also has a range of different organic and inorganic salts , having varying oxidation states ranging from (0,I) to (III).
Copper compounds, whether organic complexes or organometallics, ... Attempts to prepare copper(II) iodide yield only copper(I) iodide and iodine. [1]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The most common additive to the Stille reaction is stoichiometric or co-catalytic copper(I), specifically copper iodide, which can enhance rates up by >10 3 fold. It has been theorized that in polar solvents copper transmetalate with the organostannane. The resulting organocuprate reagent could then transmetalate with the palladium catalyst.
Marshite (CuI) is a naturally occurring isometric halide mineral with occasional silver (Ag) substitution for copper (Cu). [6] [7] Solid solution between the silver end-member miersite and the copper end-member marshite has been found in these minerals from deposits in Broken Hill, Australia. [8]
The addition of Grignard reagents to alkynes is facilitated by a catalytic amount of copper halide. Transmetalation to copper and carbocupration are followed by transmetalation of the product alkene back to magnesium. The addition is syn unless a coordinating group is nearby in the substrate, in which case the addition becomes anti and yields ...
The two most common zinc functional group interconversion reactions are with halides and boron, which is catalyzed by copper iodide (CuI) or base. The boron intermediate is synthesized by an initial hydroboration reaction followed by treatment with diethyl zinc. This synthesis shows the utility of organozinc reagents by displaying high ...