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The Zeisel determination or Zeisel test is a chemical test for the presence of esters or ethers in a chemical substance. [1] [2] [3] [4]It is named after the Czech chemist Simon Zeisel (1854–1933).
Gutmann, a chemist renowned for his work on non-aqueous solvents, described an acceptor-number scale for solvent Lewis acidity [4] with two reference points relating to the 31 P NMR chemical shift of Et 3 PO in the weakly Lewis acidic solvent hexane (δ = 41.0 ppm, AN 0) and in the strongly Lewis acidic solvent SbCl 5 (δ = 86.1 ppm, AN 100).
The numbers are included in the name to avoid ambiguity about the position of the groups, and "tri" indicates that there are three identical methyl groups. If one of the methyl groups attached to the third carbon atom were instead an ethyl group, then the name would be 3-ethyl-2,3-dimethylpentane.
5.3 Diethyl. Toggle the table of contents. ... 3-Ethyl-3-methylhexane; 3-Ethyl-4-methylhexane; Pentane. Isomers where pentane is the longest chain Tetramethyl
Hagemann's ester, ethyl 2-methyl-4-oxo-2-cyclohexenecarboxylate, is an organic compound that was first prepared and described in 1893 by German chemist Carl Hagemann. The compound is used in organic chemistry as a reagent in the synthesis of many natural products including sterols , trisporic acids , and terpenoids .
3-Ethylpentane (C 7 H 16) is a branched saturated hydrocarbon. It is an alkane, and one of the many structural isomers of heptane, consisting of a five carbon chain with a two carbon branch at the middle carbon. An example of an alcohol derived from 3-ethylpentane is the tertiary alcohol 3-ethylpentan-3-ol. [3]
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It can be produced by a Friedel-Crafts alkylation between 1-chlorohexane and benzene., [1] or by the reaction of benzene and 1-hexene with various acid catalysts such as antimony pentafluoride, [2] scandium(III) triflate, [3] and phosphoric acid. [4]