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Technetium(IV) chloride is the inorganic compound with the formula TcCl 4.It was discovered in 1957 as the first binary halide of technetium. It is the highest oxidation binary chloride of technetium that has been isolated as a solid.
It has a bioctahedral structure, consisting of triangular Tc 3 Cl 9 units with C 3v symmetry, with each Tc atom coordinated to two Tc neighbors and five chloride ligands (Tc-Tc bond length 2.44 angstrom). The Tc-Tc distances are indicative of double bonded Tc atoms. Tc 3 Cl 9 is isostructural to its rhenium homologue, trirhenium nonachloride. [1]
Ninety-five songs have charted in the top ten of the Irish Singles Chart in 2021. Of these, eighty-six songs have reached their peak during 2021. Irish singer-songwriter Dermot Kennedy and Italian producers Meduza took the first number one single of the year, with their track "Paradise".
"The Spark" is a song by the Irish children's hip hop groups Kabin Crew and Lisdoonvarna Crew. It was first released as a music video on 16 May 2024 by Creative Ireland—an Irish government organization that organizes Cruinniú na nÓg, an annual day dedicated to children's creativity—and later released as a single onto streaming platforms by Rubyworks Records on 13 June 2024.
1 3 May 4 Kendrick Lamar "Not Like Us" 7 17 May - [16] Tommy Richman "Million Dollar Baby" 5 17 May - Post Malone featuring Morgan Wallen "I Had Some Help" 1 17 May 1 Billie Eilish "Chihiro" 7 24 May - [17] "Lunch" 4 31 May - [18] Shaboozey "A Bar Song (Tipsy)" 1 31 May 1 Central Cee and Lil Baby "Band4Band" 9 7 June - [19] Eminem "Houdini" 2 7 ...
[1] [2] It tells the story of Grace Gifford's marriage to Joseph Plunkett in Kilmainham Jail, hours before his execution in 1916. [3] It was released as a single by Jim McCann and reached number 2 in the Irish charts, staying in the charts for 33 weeks from 1 April 1986. [4] [5] Jim McCann described it as: A good new song about an old subject. [1]
O'Connell began her professional musical journey during a six-week tour of the US in 1980, as vocalist for the traditionally-based Celtic group De Dannan.The following year, she was featured on the band's landmark album, The Star Spangled Molly, (where she has the lead vocals on four tracks) which became something of a national phenomenon in her homeland. [2]
This saw Podge and Rodge cut to a commercial whilst Donna and Joseph sang their new song and return from the break when the song was finished. The episode was heavily criticised and later, co-host Lucy Kennedy insisted they show a recorded version of the performance, only to find Rodge had recorded lesbian kissing scenes over the tape.