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Coumaphos is a nonvolatile, fat-soluble phosphorothioate with ectoparasiticide properties: it kills insects and mites. It is well known by a variety of brand names as a dip or wash, used on farm and domestic animals to control ticks, mites, flies and fleas.
Sheep dip is a liquid formulation of insecticide and fungicide that shepherds and farmers use to protect their sheep from infestation against external parasites such as itch mite (Psoroptes ovis), blow-fly, ticks and lice.
Phosmet is a phthalimide-derived, non-systemic, organophosphate insecticide used on plants and animals. It is mainly used on apple trees for control of codling moth, though it is also used on a wide range of fruit crops, ornamentals, and vines for the control of aphids, suckers, [clarification needed] mites, and fruit flies.
When aliphatic alcohols are used the HCl by-product can react with the phosphate esters to give organochlorides and a lower ester. O=P(OR) 3 + HCl → O=P(OR) 2 OH + RCl. This reaction is usually undesirable and is exacerbated by high reaction temperatures. It can be inhibited by the use of a base or the removal of HCl through sparging.
Grave of William Cooper in Berkhamsted Coopers sheep dip advert 1871. William Cooper (26 December 1813 – 20 May 1885) was a British veterinary surgeon, agriculturalist and industrialist who specialised in the manufacture of agricultural insecticides for livestock. He is credited with developing the first successful sheep dip, Cooper's Dip, in ...
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