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Chlorine dioxide is also superior to chlorine when operating above pH 7, [17]: 4–33 in the presence of ammonia and amines, [28] and for the control of biofilms in water distribution systems. [25] Chlorine dioxide is used in many industrial water treatment applications as a biocide, including cooling towers, process water, and food processing ...
The chlorite ion adopts a bent molecular geometry, due to the effects of the lone pairs on the chlorine atom, with an O–Cl–O bond angle of 111° and Cl–O bond lengths of 156 pm. [1] Chlorite is the strongest oxidiser of the chlorine oxyanions on the basis of standard half cell potentials.
The name can also refer to esters of hypochlorous acid, namely organic compounds with a ClO– group covalently bound to the rest of the molecule. The principal example is tert-butyl hypochlorite, which is a useful chlorinating agent. [3] Most hypochlorite salts are handled as aqueous solutions.
Halazone, or 4-((dichloroamino)sulfonyl)benzoic acid, (HOOC)(C 6 H 4) (SO 2)(NCl 2). This compound was for a while used to disinfect drinking water in field situations, but has largely been replaced in that use by sodium dichloroisocyanurate. [2] Chlorine dioxide, ClO 2. [23]
Chlorous acid is an inorganic compound with the formula HClO 2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl oxidation state +5): 2 HClO 2 → HClO + HClO 3
Chlorine can be further oxidized to other oxides and oxyanions including hypochlorite (ClO −, the active ingredient in chlorine bleach), chlorine dioxide (ClO 2), chlorate (ClO − 3), and perchlorate (ClO − 4). In terms of its acid–base properties, chloride is a weak base as indicated by the negative value of the pK a of hydrochloric
Hypochlorous acid is an inorganic compound with the chemical formula Cl O H, also written as HClO, HOCl, or ClHO. [2] [3] Its structure is H−O−Cl.It is an acid that forms when chlorine dissolves in water, and itself partially dissociates, forming a hypochlorite anion, ClO −.
Evaporation under reduced pressure allows it to be concentrated further to about 40%, but then it decomposes to perchloric acid, chlorine, oxygen, water, and chlorine dioxide. Its most important salt is sodium chlorate, mostly used to make chlorine dioxide to bleach paper pulp. The decomposition of chlorate to chloride and oxygen is a common ...
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