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The partial volume of a particular gas is a fraction of the total volume occupied by the gas mixture, with unchanged pressure and temperature. In gas mixtures, e.g. air, the partial volume allows focusing on one particular gas component, e.g. oxygen.
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
V i is the partial volume, or volume of the component gas at the given pressure and temperature. Henry's law This states that at constant temperature, the amount of a given gas dissolved in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid. The equation is as follows:
Specific volume is an example of an intensive property because it is the ratio of volume occupied by a unit of mass of a gas that is identical throughout a system at equilibrium. [ 17 ] 1000 atoms a gas occupy the same space as any other 1000 atoms for any given temperature and pressure.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Specific volume is commonly applied to: Molar volume; Volume (thermodynamics) Partial molar volume; Imagine a variable-volume, airtight chamber containing a certain number of atoms of oxygen gas. Consider the following four examples: If the chamber is made smaller without allowing gas in or out, the density increases and the specific volume ...
Figure A: The surface generated by the ideal gas equation. The van der Waals equation is a mathematical formula that describes the behavior of real gases. It is named after Dutch physicist Johannes Diderik van der Waals. It is an equation of state that relates the pressure, temperature, and molar volume in a fluid.
The law is a specific case of the ideal gas law. A modern statement is: Avogadro's law states that "equal volumes of all gases, at the same temperature and pressure, have the same number of molecules." [1] For a given mass of an ideal gas, the volume and amount (moles) of the gas are directly proportional if the temperature and pressure are ...