Search results
Results from the WOW.Com Content Network
A silicon–oxygen bond (Si−O bond) is a chemical bond between silicon and oxygen atoms that can be found in many inorganic and organic compounds. [1] In a silicon–oxygen bond, electrons are shared unequally between the two atoms , with oxygen taking the larger share due to its greater electronegativity .
The general structure of a silanone. A silanone in chemistry is the silicon analogue of a ketone.The general description for this class of organic compounds is R 1 R 2 Si=O, with silicon connected to a terminal oxygen atom via a double bond and also with two organic residues (R). [1]
The Fleming–Tamao oxidation, or Tamao–Kumada–Fleming oxidation, converts a carbon–silicon bond to a carbon–oxygen bond with a peroxy acid or hydrogen peroxide. Fleming–Tamao oxidation refers to two slightly different conditions developed concurrently in the early 1980s by the Kohei Tamao and Ian Fleming research groups. [1] [2] [3]
Intermediate organization of covalent bonds: Regarding the organization of covalent bonds, recall that classic molecular solids, as stated above, consist of small, non-polar covalent molecules. The example given, paraffin wax , is a member of a family of hydrocarbon molecules of differing chain lengths, with high-density polyethylene at the ...
Thus the Si–F bond is significantly stronger than even the C–F bond and is one of the strongest single bonds, while the Si–H bond is much weaker than the C–H bond and is readily broken. Furthermore, the ability of silicon to expand its octet is not shared by carbon, and hence some organosilicon reactions have no organic analogues.
A polar bond is a covalent bond in which there is a separation of charge between one end and the other - in other words in which one end is slightly positive and the other slightly negative. Examples include most covalent bonds. The hydrogen-chlorine bond in HCl or the hydrogen-oxygen bonds in water are typical.
Moreover, the multiple bonds of the elements with n=2 are much stronger than usual, because lone pair repulsion weakens their sigma bonding but not their pi bonding. [2] An example is the rapid polymerization that occurs upon condensation of disulfur , the heavy analogue of O 2 .
Chloride is an ideal group due to the low cost of organochlorine compounds. Frequently, however, C–Cl bonds are too inert, and bromide or iodide leaving groups are required for acceptable rates. The main group metal in the organometallic partner usually is an electropositive element such as tin, zinc, silicon, or boron.