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The +M effect, also known as the positive mesomeric effect, occurs when the substituent is an electron donating group. The group must have one of two things: a lone pair of electrons, or a negative charge. In the +M effect, the pi electrons are transferred from the group towards the conjugate system, increasing the density of the system.
The pEDA parameter (pi electron donor-acceptor) is a pi-electron substituent effect scale, described also as mesomeric or resonance effect. There is also a complementary scale - sEDA. The more positive is the value of pEDA the more pi-electron donating is a substituent.
In experiment, the incident beam that produces resonance always has some spread of energy around a central value. Usually, that is a Gaussian/normal distribution.The resulting resonance shape in this case is given by the convolution of the Breit–Wigner and the Gaussian distribution,
Helmholtz resonance, also known as wind throb, refers to the phenomenon of air resonance in a cavity, an effect named after the German physicist Hermann von Helmholtz. [1] This type of resonance occurs when air is forced in and out of a cavity (the resonance chamber ), causing the air inside to vibrate at a specific natural frequency .
Resonance effect in electrical machines [ edit ] In radial flux rotating electric machines, resonance due to electromagnetic forces is particular as it occurs at two conditions: there must be a match between the exciting Maxwell force and the stator or rotor natural frequency, and between the stator or rotor modal shape and the exciting Maxwell ...
However, resonance can also be detrimental, leading to excessive vibrations or even structural failure in some cases. [3] All systems, including molecular systems and particles, tend to vibrate at a natural frequency depending upon their structure; this frequency is known as a resonant frequency or resonance frequency.
Average mortgage rates tick higher as of Thursday, January 9, 2024, with the 30-year fixed benchmark continuing to hover above 7.00%. Despite three back-to-back interest cuts from the Federal ...
The global electromagnetic resonance phenomenon is named after physicist Winfried Otto Schumann who predicted it mathematically in 1952. Schumann resonances are the principal background in the part of the electromagnetic spectrum [2] from 3 Hz through 60 Hz [3] and appear as distinct peaks at extremely low frequencies around 7.83 Hz (fundamental), 14.3, 20.8, 27.3, and 33.8 Hz.
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