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The two dominant resonance forms of the phosphaethynolate anion localise negative charge on either the phosphorus or oxygen atoms meaning both are sites of nucleophilicity. [11] The same applies for the cyanate anion hence why PCO is observed to have similar pseudo-halogenic behaviour.
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
Alkali metals form ionic and highly soluble monofluorides; these have the cubic arrangement of sodium chloride and analogous chlorides. [ 102 ] [ 103 ] Alkaline earth difluorides possess strong ionic bonds but are insoluble in water, [ 86 ] with the exception of beryllium difluoride , which also exhibits some covalent character and has a quartz ...
In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound. It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [ 1 ]
The Minnaert resonance [1] [2] [3] is a phenomenon associated with a gas bubble pulsating at its natural frequency in a liquid, neglecting the effects of surface tension and viscous attenuation. It is the frequency of the sound made by a drop of water from a tap falling in water underneath, trapping a bubble of air as it falls.
Expressing resonance when drawing Lewis structures may be done either by drawing each of the possible resonance forms and placing double-headed arrows between them or by using dashed lines to represent the partial bonds (although the latter is a good representation of the resonance hybrid which is not, formally speaking, a Lewis structure).
HF is miscible with water (will dissolve in any proportion), while the other hydrogen halides have large solubility gaps with water. Hydrogen fluoride and water also form several compounds in the solid state, most notably a 1:1 compound that does not melt until −40 °C (−40 °F), which is 44 degrees Celsius (79 degrees Fahrenheit) above the ...
Clar's rule states that for a benzenoid polycyclic aromatic hydrocarbon (i.e. one with only hexagonal rings), the resonance structure with the largest number of disjoint aromatic π-sextets is the most important to characterize its chemical and physical properties. Such a resonance structure is called a Clar structure. In other words, a ...