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The olefins contained an EWG nitrile group and varying EDGs and the effect of varying EDGs on the rate of the addition reactions was observed. The process studied was: The process studied was: The rate of the addition reaction was accelerated by the following EDGs in increasing order: H < CH 3 < OCH 2 CH 3 .
In 1993, the Environmental Working Group was founded by Ken Cook and Richard Wiles. [1] EWG is headquartered in Washington, D.C.. [2] Its lobbying organization, the EWG Action Fund (a 501(c)(4) organization) was founded in 2002. [3] EWG partners with companies to certify their products. [4]
A nitroalkene, or nitro olefin, is a functional group combining the functionality of its constituent parts, an alkene and nitro group, while displaying its own chemical properties through alkene activation, making the functional group useful in specialty reactions such as the Michael reaction or Diels-Alder additions.
One variant of the reaction involves iminodiacetonitrile or iminodiacetic acid (step 1'), which reacts in a weakly acidic medium (pH 6) with hydrogen cyanide and ethanal to form methylglycinonitrile-N,N-diacetic acid, the nitrile group of which is hydrolyzed with sodium hydroxide to trisodium N-(1-carboxylatoethyl)iminodiacetate (step 2').
Its molecular structure consists of a vinyl group (−CH=CH 2) linked to a nitrile (−C≡N). It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. It is reactive and toxic at low doses. [5] Acrylonitrile is one of the components of ABS plastic (acrylonitrile butadiene styrene). [6]
This page was last edited on 6 March 2011, at 06:10 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
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