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It is rapidly transformed into grey arsenic by light. The yellow form has a density of 1.97 g/cm 3. [23] Black arsenic is similar in structure to black phosphorus. [23] Black arsenic can also be formed by cooling vapor at around 100–220 °C and by crystallization of amorphous arsenic in the presence of mercury vapors. [26] It is glassy and ...
When administered intravenously, a steady state is reached after 8–10 days. Arsenic binds to proteins to an insignificant extent. The highest concentrations of arsenic are found in the liver, kidneys, heart, lungs, hair, and nails. Arsenous acid is oxidized to arsenic acid and methylated in the liver, [65] [66] [67] and then excreted 60% in ...
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
The X-phase and the H-phase are only stable above 2000 K. At lower temperatures, there are the hexagonal A-phase, the monoclinic B-phase, and the cubic C-phase, which is the stable form at room temperature for most of the elements. The C-phase was once thought to be in space group I2 1 3 (no. 199), [31] but is now known to be in space group Ia ...
In all of these the geometry around the As III centers are approximately trigonal, the lone pair on the arsenic atom is stereochemically active. [1] Well known examples of arsenites include sodium meta-arsenite which contains a polymeric linear anion, (AsO − 2) n, and silver ortho-arsenite, Ag 3 AsO 3, which contains the trigonal AsO 3− 3 ...
Despite the well known toxicity of arsenic, arsenic trioxide was used in traditional Chinese medicine, where it is known as pi-shuang (Chinese: 砒霜; pinyin: pīshuāng; lit. 'arsenic frost'). In homeopathy, it is called arsenicum album. Some discredited patent medicines, e.g., Fowler's solution, contained derivatives of arsenic oxide. [20]
The first breakthrough in the detection of arsenic poisoning was in 1775 when Carl Wilhelm Scheele discovered a way to change arsenic trioxide to garlic-smelling arsine gas (AsH 3), by treating it with nitric acid (HNO 3) and combining it with zinc. [3] As 2 O 3 + 6 Zn + 12 HNO 3 → 2 AsH 3 + 6 Zn(NO 3) 2 + 3 H 2 O
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]