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Real gases are non-ideal gases whose molecules occupy space and have interactions; consequently, they do not adhere to the ideal gas law. To understand the behaviour of real gases, the following must be taken into account: compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects;
For real gases the equation of state will depart from the simpler one, and the result above derived for an ideal gas will only be a good approximation provided that (a) the typical size of the molecule is negligible compared to the average distance between the individual molecules, and (b) the short range behavior of the inter-molecular ...
The van der Waals interactions between gas molecules, is the reason why modeling a "real gas" is more mathematically difficult than an "ideal gas". Ignoring these proximity-dependent forces allows a real gas to be treated like an ideal gas, which greatly simplifies calculation. Isothermal curves depicting the non-ideality of a real gas.
The van der Waals equation is a mathematical formula that describes the behavior of real gases. It is named after Dutch physicist Johannes Diderik van der Waals . It is an equation of state that relates the pressure , temperature , and molar volume in a fluid .
At high pressures, the volume of a real gas is often considerably larger than that of an ideal gas. At low temperatures, the pressure of a real gas is often considerably less than that of an ideal gas. At some point of low temperature and high pressure, real gases undergo a phase transition, such as to a liquid or a solid. The model of an ideal ...
For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated. Alternatively, the compressibility factor for specific gases can be read from generalized compressibility charts [ 1 ] that plot Z {\displaystyle Z} as a function of pressure at ...
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Avogadro's law (sometimes referred to as Avogadro's hypothesis or Avogadro's principle) or Avogadro-Ampère's hypothesis is an experimental gas law relating the volume of a gas to the amount of substance of gas present. [1] The law is a specific case of the ideal gas law. A modern statement is: