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  2. Methylidyne radical - Wikipedia

    en.wikipedia.org/wiki/Methylidyne_radical

    The trivial name carbyne is the preferred IUPAC name. Following the substitutive nomenclature, the molecule is viewed as methane with three hydrogen atoms removed, yielding the systematic name "methylidyne". Following the additive nomenclature, the molecule is viewed as a hydrogen atom bonded to a carbon atom, yielding the name "hydridocarbon".

  3. Electron pair - Wikipedia

    en.wikipedia.org/wiki/Electron_pair

    This also limits the number of electrons in the same orbital to two. The pairing of spins is often energetically favorable, and electron pairs therefore play a large role in chemistry. They can form a chemical bond between two atoms, or they can occur as a lone pair of valence electrons. They also fill the core levels of an atom.

  4. Lewis structure - Wikipedia

    en.wikipedia.org/wiki/Lewis_structure

    The seventh lone pair must be placed on the nitrogen atom. Satisfy the octet rule. Both oxygen atoms currently have 8 electrons assigned to them. The nitrogen atom has only 6 electrons assigned to it. One of the lone pairs on an oxygen atom must form a double bond, but either atom will work equally well. Therefore, there is a resonance structure.

  5. Ion association - Wikipedia

    en.wikipedia.org/wiki/Ion_association

    In chemistry, ion association is a chemical reaction whereby ions of opposite electric charge come together in solution to form a distinct chemical entity. [1] [2] Ion associates are classified, according to the number of ions that associate with each other, as ion pairs, ion triplets, etc. Ion pairs are also classified according to the nature of the interaction as contact, solvent-shared or ...

  6. Methenium - Wikipedia

    en.wikipedia.org/wiki/Methenium

    In organic chemistry, methenium (also called methylium, carbenium, [2] methyl cation, or protonated methylene) is a cation with the formula CH + 3.It can be viewed as a methylene radical (: CH

  7. Lewis acids and bases - Wikipedia

    en.wikipedia.org/wiki/Lewis_acids_and_bases

    Lewis had suggested in 1916 that two atoms are held together in a chemical bond by sharing a pair of electrons. [18] When each atom contributed one electron to the bond, it was called a covalent bond. When both electrons come from one of the atoms, it was called a dative covalent bond or coordinate bond. The distinction is not very clear-cut.

  8. Molecular orbital diagram - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_diagram

    Distributing 8 electrons over 6 molecular orbitals leaves the final two electrons as a degenerate pair in the 2pπ* antibonding orbitals resulting in a bond order of 2. As in diboron, these two unpaired electrons have the same spin in the ground state, which is a paramagnetic diradical triplet oxygen.

  9. Ligand - Wikipedia

    en.wikipedia.org/wiki/Ligand

    One lone pair is used as a sigma X donor, the other two lone pairs are available as L-type pi donors. If both lone pairs are used in pi bonds then the M−N−R geometry is linear. However, if one or both these lone pairs is nonbonding then the M−N−R bond is bent and the extent of the bend speaks to how much pi bonding there may be.