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Phase behavior Triple point: 267.13 K (–6.02 °C), ? Pa Critical point: 698.8 K (425.7 °C), 4890 kPa Std enthalpy change of fusion, Δ fus H o: 10.54 kJ/mol Std entropy change of fusion, Δ fus S o: 39.57 J/(mol·K) at –6.3 °C Std enthalpy change of vaporization, Δ vap H o: 55.83 kJ/mol at 25 °C 42.44 kJ/mol at 184.1 °C Std entropy change
Std entropy change of fusion, Δ fus S o: 55.27 J/(mol·K) (189.3 K) Std enthalpy change of vaporization, Δ vap H o: 31.94 kJ/mol Std entropy change of vaporization, Δ vap S o: 103.35 J/(mol·K) Solid properties Std enthalpy change of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K ...
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
Table of specific heat capacities at 25 °C (298 K) unless otherwise noted. [citation needed] Notable minima and maxima are shown in maroon. Substance Phase Isobaric mass heat capacity c P J⋅g −1 ⋅K −1 Molar heat capacity, C P,m and C V,m J⋅mol −1 ⋅K −1 Isobaric volumetric heat capacity C P,v J⋅cm −3 ⋅K −1 Isochoric ...
The other two common states of matter of water are the solid phase, ice, and the gaseous phase, water vapor or steam. The addition or removal of heat can cause phase transitions: freezing (water to ice), melting (ice to water), vaporization (water to vapor), condensation (vapor to water), sublimation (ice to vapor) and deposition (vapor to ice ...
Silicon (phase change) 1.790 4.5 500 1,285 Energy stored through solid to liquid phase change of silicon [88] Strontium bromide hydrate: 0.814 [89] 1.93 628 Thermal energy of phase change at 88.6 °C (361.8 K) Liquid nitrogen: 0.77 [90] 0.62 213.9 172.2 Maximum reversible work at 77.4 K with 300 K reservoir Compressed air at 30 MPa (4,400 psi ...
For each kind of change under specified conditions, the heat capacity is the ratio of the quantity of heat transferred to the magnitude of the change. [65] For example, if the change is an increase in temperature at constant volume, with no phase change and no chemical change, then the temperature of the body rises and its pressure increases.
The glass transition of a liquid to a solid-like state may occur with either cooling or compression. [10] The transition comprises a smooth increase in the viscosity of a material by as much as 17 orders of magnitude within a temperature range of 500 K without any pronounced change in material structure. [11]