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Strong acids such as hydrochloric acid can, however, protonate indole. Indole is primarily protonated at the C3, rather than N1, owing to the enamine-like reactivity of the portion of the molecule located outside of the benzene ring. The protonated form has a pK a of −3.6.
The nitrogen (N)-containing aromatic rings can be separated into basic aromatic rings that are easily protonated, and form aromatic cations and salts (e.g., pyridinium), and non-basic aromatic rings. In the basic aromatic rings, the lone pair of electrons is not part of the aromatic system and extends in the plane of the ring.
The first step in polar transport is auxin influx. Auxin enters plant cells by two methods, first by passive diffusion as non-ionized protonated indole-3-acetic acid (IAAH) across the phospholipid bilayer, or second by active co-transport in the anionic form IAA −. As IAAH is lipophilic, it can easily cross the lipid bilayer.
Histidine ball and stick model spinning. Histidine (symbol His or H) [2] is an essential amino acid that is used in the biosynthesis of proteins.It contains an α-amino group (which is in the protonated –NH 3 + form under biological conditions), a carboxylic acid group (which is in the deprotonated –COO − form under biological conditions), and an imidazole side chain (which is partially ...
Protonation is usually reversible, and the structure and bonding of the conjugate base are normally unchanged on protonation. In some cases, however, protonation induces isomerization, for example cis-alkenes can be converted to trans-alkenes using a catalytic amount of protonating agent.
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Basic aromatic compounds get protonated and form aromatic cations (e.g. pyridinium) under acidic conditions. Typical examples of basic aromatic rings are pyridine or quinoline. Several rings contain basic as well as non-basic nitrogen atoms, e.g. imidazole and purine.
Renée Zellweger took a step back from acting for a six-year stretch in the 2010s, and she's opening up about the reason for her hiatus.. The Oscar-winning "Bridget Jones's Diary" actress, 55 ...