Search results
Results from the WOW.Com Content Network
The cyclopentadienyl anion is a planar, cyclic, regular-pentagonal ion; it has 6 π-electrons (4n + 2, where n = 1), which fulfills Hückel's rule of aromaticity. Each double bond and lone pair provides 2 π-electrons, which are delocalized into the ring. [4] Cyclopentadiene has a pKa of about 16.
In chemistry, cyclopentadienyl is a radical with the formula C 5 H 5. The related cyclopentadienyl anion (which can formally be converted to the cyclopentadienyl radical by one-electron reduction) is aromatic , and forms salts and coordination compounds .
Cyclopentadiene is an organic compound with the formula C 5 H 6. [6] It is often abbreviated CpH because the cyclopentadienyl anion is abbreviated Cp −.. This colorless liquid has a strong and unpleasant odor.
For example, the aromatic species 1 can be reduced to 2 with a relatively small penalty for forming an antiaromatic system. The antiaromatic 2 does revert to the aromatic species 1 over time by reacting with oxygen in the air because the aromaticity is preferred. [15] The loss of antiaromaticity can sometimes be the driving force of a reaction.
A cyclopentadienyl complex is a coordination complex of a metal and cyclopentadienyl groups (C 5 H − 5, abbreviated as Cp −). Cyclopentadienyl ligands almost invariably bind to metals as a pentahapto (η 5-) bonding mode. The metal–cyclopentadienyl interaction is typically drawn as a single line from the metal center to the center of the ...
Cyclopentadienyl can refer to Cyclopentadienyl anion, ... Cyclopentadienyl cation, [C 5 H 5] + See also. Pentadienyl This page was last edited on 3 July 2021 ...
Heteroarenes are aromatic compounds, where at least one methine or vinylene (-C= or -CH=CH-) group is replaced by a heteroatom: oxygen, nitrogen, or sulfur. [3] Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one ...
The cyclopentadienyl anion (C 5 H – 5) with six π electrons is planar and readily generated from the unusually acidic cyclopentadiene (pK a 16), while the corresponding cation with four π electrons is destabilized, being harder to generate than a typical acyclic pentadienyl cations and is thought to be antiaromatic. [8] Similarly, the ...