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Using his extensive measurements of the properties of gases, [6] [7] Mendeleev also calculated it with high precision, within 0.3% of its modern value. [ 8 ] The gas constant occurs in the ideal gas law: P V = n R T = m R s p e c i f i c T {\displaystyle PV=nRT=mR_{\rm {specific}}T} where P is the absolute pressure , V is the volume of gas, n ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Here because is a multivalued function, the integral must be divided into 3 parts corresponding to the 3 real roots of the vdW equation in the form, (,) (this can be visualized most easily by imagining Fig. 1 rotated ); the result is a special case of material equilibrium. [62]
There is a 1:1 molar ratio of NH 3 to NO 2 in the above balanced combustion reaction, so 5.871 mol of NO 2 will be formed. We will employ the ideal gas law to solve for the volume at 0 °C (273.15 K) and 1 atmosphere using the gas law constant of R = 0.08206 L·atm·K −1 ·mol −1:
Although Boltzmann first linked entropy and probability in 1877, the relation was never expressed with a specific constant until Max Planck first introduced k, and gave a more precise value for it (1.346 × 10 −23 J/K, about 2.5% lower than today's figure), in his derivation of the law of black-body radiation in 1900–1901. [11]
Here the 'IEEE 754 double value' resulting of the 15 bit figure is 3.330560653658221E-15, which is rounded by Excel for the 'user interface' to 15 digits 3.33056065365822E-15, and then displayed with 30 decimals digits gets one 'fake zero' added, thus the 'binary' and 'decimal' values in the sample are identical only in display, the values ...
For example, the logarithm of 1000 to base 10 is 3, because 1000 is 10 to the 3 rd power: 1000 = 10 3 = 10 × 10 × 10. More generally, if x = b y, then y is the logarithm of x to base b, written log b x, so log 10 1000 = 3. As a single-variable function, the logarithm to base b is the inverse of exponentiation with base b.
The term absolute value has been used in this sense from at least 1806 in French [3] and 1857 in English. [4] The notation | x |, with a vertical bar on each side, was introduced by Karl Weierstrass in 1841. [5] Other names for absolute value include numerical value [1] and magnitude. [1]