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Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. [1] Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with other positively charged particles in the surrounding soil water. [ 2 ]
An advantage of this method is that exchangeable cations can be removed by passing a chloride solution through the plate once the sample has been dried. Exchanging cations can be useful when establishing peaks for standards with variable interlayer cations. For example, nontronite has an interlayer which can contain both calcium and sodium. If ...
There are also amphoteric exchangers that are able to exchange both cations and anions simultaneously. However, the simultaneous exchange of cations and anions is often performed in mixed beds, which contain a mixture of anion- and cation-exchange resins, or passing the solution through several different ion-exchange materials. Ion exchanger.
Stilbite shows a wide variation in exchangeable cations: silicon and aluminium ions occupy equivalent sites and can substitute for each other. Since silicon and aluminium have a different charge (Si 4+ and Al 3+ ) the ions occupying the sodium/calcium site have to adjust to maintain charge balance.
The sodium adsorption ratio (SAR) is an irrigation water quality parameter used in the management of sodium-affected soils.It is an indicator of the suitability of water for use in agricultural irrigation, as determined from the concentrations of the main alkaline and earth alkaline cations present in the water.
LX Lixisol (low-activity clays, exchangeable base cations ≥ exchangeable Al) AL Alisol (high-activity clays, exchangeable Al > exchangeable base cations) LV Luvisol (high-activity clays, exchangeable base cations ≥ exchangeable Al) Note: The exchangeable base cations are given in cmol c kg −1. Soils with little or no profile differentiation
Montmorillonite is a subclass of smectite, a 2:1 phyllosilicate mineral characterized as having greater than 50% octahedral charge; its cation exchange capacity is due to isomorphous substitution of Mg for Al in the central alumina plane. The substitution of lower valence cations in such instances leaves the nearby oxygen atoms with a net ...
Exchangeable cations are present in the clay minerals interlayers and on the external basal planes of clay platelets. Cations also compensate the negative charges on the clay particle edges caused by the protolysis of silanol and aluminol groups ( pH dependent charges).