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Alteration of hardened cement paste composition, with monosulfate aluminates phase converting to ettringite and, in later stages, gypsum formation. The necessary additional calcium is provided by the calcium hydroxide and calcium silicate hydrate in the cement paste; The effect of these changes is an overall loss of concrete strength.
This reaction is exothermic and is responsible for the ease with which gypsum can be cast into various shapes including sheets (for drywall), sticks (for blackboard chalk), and molds (to immobilize broken bones, or for metal casting). Mixed with polymers, it has been used as a bone repair cement.
The rate of initial reaction (up to 24 hours) of the cement on addition of water is directly proportional to the specific surface area. Typical values are 320–380 m 2 ·kg −1 for general purpose cements, and 450–650 m 2 ·kg −1 for 'rapid hardening' cements. The cement is conveyed by belt or powder pump to a silo for storage.
Gypsum is a common mineral, with thick and extensive evaporite beds in association with sedimentary rocks. Deposits are known to occur in strata from as far back as the Archaean eon. [16] Gypsum is deposited from lake and sea water, as well as in hot springs, from volcanic vapors, and sulfate solutions in veins.
Portland cement clinker (abbreviated k in the European norms) is ground to a fine powder and used as the binder in many cement products. A small amount of gypsum (less than 5 wt.%) must be added to avoid the flash setting of the tricalcium aluminate (Ca 3 Al 2 O 6 ), the most reactive mineral phase (exothermic hydration reaction) in Portland ...
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most ...
Gypsum is easily washed away in wastewater causing a loss of concrete aggregate and exposing fresh material to acid attack. Concrete floors lying on ground that contains pyrite (iron(II) disulfide) are also at risk. As a preventive measure sewage may be pretreated to increase pH or oxidize or precipitate the sulfides in order to minimize the ...
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...