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The catalyst responsible for this conversion, RuBisCO, is the most common protein. Some anaerobic organisms employ enzymes to convert CO 2 to carbon monoxide, from which fatty acids can be made. [11] In industry, a few products are made from CO 2, including urea, salicylic acid, methanol, and certain inorganic and organic carbonates. [12]
Single electron reduction of CO 2 to CO 2 − radical occurs at E° = −1.90 V versus NHE at pH = 7 in an aqueous solution at 25 °C under 1 atm gas pressure. The reason behind the high negative thermodynamically unfavorable single electron reduction potential of CO 2 is the large reorganization energy between the linear molecule and bent ...
The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...
The formal standard reduction potential ′ can be defined as the measured reduction potential of the half-reaction at unity concentration ratio of the oxidized and reduced species (i.e., when C red / C ox = 1) under given conditions.
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log 10 (K eq) has a value of zero at approx. 975 K. The implication of the change in K eq with temperature is that a gas containing CO may form elemental carbon if the mixture cools below a certain temperature. The thermodynamic activity of carbon may be calculated for a CO / CO 2 mixture by knowing the partial pressure of each species and the ...
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Other photosensitizers have also been employed as catalysts. They include FeTPP (TPP=5,10,15,20-tetraphenyl-21H,23H-porphine) and CoTPP, both of which produce CO while the latter produces formate also. Non-metal photocatalysts include pyridine and N-heterocyclic carbenes. [7] [8] A reaction scheme for the catalytic reduction of CO 2 by Re(bpy ...