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The Flory theory of rubber elasticity suggests that rubber elasticity has primarily entropic origins. By using the following basic equations for Helmholtz free energy and its discussion about entropy, the force generated from the deformation of a rubber chain from its original unstretched conformation can be derived.
The model is based on Ronald Rivlin's observation that the elastic properties of rubber may be described using a strain energy density function which is a power series in the strain invariants,, of the Cauchy-Green deformation tensors. [2] The Yeoh model for incompressible rubber is a function only of .
Contact mechanics is the study of the deformation of solids that touch each other at one or more points. [1] [2] A central distinction in contact mechanics is between stresses acting perpendicular to the contacting bodies' surfaces (known as normal stress) and frictional stresses acting tangentially between the surfaces (shear stress).
The Gent hyperelastic material model [1] is a phenomenological model of rubber elasticity that is based on the concept of limiting chain extensibility. In this model, the strain energy density function is designed such that it has a singularity when the first invariant of the left Cauchy-Green deformation tensor reaches a limiting value .
The most common example of this kind of material is rubber, whose stress-strain relationship can be defined as non-linearly elastic, isotropic and incompressible. Hyperelasticity provides a means of modeling the stress–strain behavior of such materials. [2] The behavior of unfilled, vulcanized elastomers often conforms closely to the ...
Elastic response of rubber-like materials are often modeled based on the Mooney–Rivlin model. The constants , are determined by fitting the predicted stress from the above equations to the experimental data. The recommended tests are uniaxial tension, equibiaxial compression, equibiaxial tension, uniaxial compression, and for shear, planar ...
The T-V diagram of the rubber band experiment. The decrease in the temperature of the rubber band in a spontaneous process at ambient temperature can be explained using the Helmholtz free energy = where dF is the change in free energy, dL is the change in length, τ is the tension, dT is the change in temperature and S is the entropy.
In continuum mechanics, an Arruda–Boyce model [1] is a hyperelastic constitutive model used to describe the mechanical behavior of rubber and other polymeric substances. This model is based on the statistical mechanics of a material with a cubic representative volume element containing eight chains along the diagonal directions.