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Iodate is one of several oxyanions of iodine, and has an oxidation number of +5. It participates in several redox reactions, such as the iodine clock reaction. Iodate shows no tendency to disproportionate to periodate and iodide, in contrast to the situation for chlorate. Iodate is reduced by sulfite: [1] 6HSO − 3 + 2IO − 3 → 2I − ...
The structure consists of pyramidal molecules linked by hydrogen bonding and intermolecular iodine-oxygen interactions. The I=O bond lengths are 1.81 Å while the I–OH distance is 1.89 Å. [ 4 ] [ 5 ] [ 6 ] Several other polymorphs have been reported, including an orthorhombic γ form in space group Pbca [ 7 ] and an orthorhombic δ form in ...
The main use of sodium iodate in everyday life is in iodised salt. The other compounds which are used in iodised table salt are potassium iodate, potassium iodide, and sodium iodide. Sodium iodate comprises 15 to 50 mg per kilogram of applicable salt. Sodium iodate is also used as a dough conditioner to strengthen the dough.
By the same token, however, since iodine has the lowest ionisation energy among the halogens and is the most easily oxidised of them, it has a more significant cationic chemistry and its higher oxidation states are rather more stable than those of bromine and chlorine, for example in iodine heptafluoride. [1]
A fluorooxoiodate or fluoroiodate is a chemical compound or ion derived from iodate, by substituting some of the oxygen by fluorine. They have iodine in the +5 oxidation state. The iodine atoms have a stereochemically active lone-pair of electrons.
In a λ 3 ‑iodane, each X-type ligand donates an additional electron, for 10 in total; the result is a decet structure. Similarly, many λ 5 ‑iodanes are dodecet molecules, and hypothetical λ 7 ‑iodanes are tetradecet molecules. As with other hypervalent compounds, N‑X‑L notation can be used to describe the formal electron count of ...
Potassium iodate may be used to protect against accumulation of radioactive iodine in the thyroid by saturating the body with a stable source of iodine prior to exposure. [9] Approved by the World Health Organization for radiation protection, potassium iodate (KIO 3 ) is an alternative to potassium iodide (KI) , which has poor shelf life in hot ...
A typical example of a Lewis acid in action is in the Friedel–Crafts alkylation reaction. [5] The key step is the acceptance by AlCl 3 of a chloride ion lone-pair, forming AlCl − 4 and creating the strongly acidic, that is, electrophilic, carbonium ion. RCl +AlCl 3 → R + + AlCl − 4