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Raman spectroscopy (/ ˈ r ɑː m ən /) (named after physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. [1] Raman spectroscopy is commonly used in chemistry to provide a structural fingerprint by which ...
Raman spectroscopy employs the Raman effect for substances analysis. The spectrum of the Raman-scattered light depends on the molecular constituents present and their state, allowing the spectrum to be used for material identification and analysis. Raman spectroscopy is used to analyze a wide range of materials, including gases, liquids, and ...
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Resonance hyper-Raman spectroscopy: Excitation of the sample occurs by two-photon absorption, rather than by absorption of a single photon. This arrangement allows for excitation of modes that are forbidden in ordinary resonance Raman spectroscopy, with intensity enhancement due to resonance, and also simplifies collection of scattered light ...
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Rotational–vibrational spectroscopy is a branch of molecular spectroscopy that is concerned with infrared and Raman spectra of molecules in the gas phase. Transitions involving changes in both vibrational and rotational states can be abbreviated as rovibrational (or ro-vibrational ) transitions.
In Raman-SEC, the light source is usually a laser corresponding to the VIS or NIR regions, which commonly emits at 532, 633, 785 or 1064 nm, [4] although there is the possibility of using many other lasers, including UV-lasers. Spectrometer. It records the scattered radiation and provides the Raman spectra of the molecules.
A Raman band whose depolarization ratio is less than 0.75 is called a polarized band, and a band with a depolarization ratio equal to or greater than 0.75 is called a depolarized band. [4] [5] For a spherical top molecule in which all three axes are equivalent, symmetric vibrations have Raman spectral bands which are completely polarized (ρ = 0).