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In organic chemistry, butyl is a four-carbon alkyl radical or substituent group with general chemical formula −C 4 H 9, derived from either of the two isomers (n-butane and isobutane) of butane. The isomer n -butane can connect in two ways, giving rise to two "-butyl" groups:
It is commonly abbreviated as TBSCl or TBDMSCl. It is a chlorosilane containing two methyl groups and a tert-butyl group. As such it is more bulky that trimethylsilyl chloride. It is a colorless or white solid that is soluble in many organic solvents but reacts with water and alcohols. The compound is used to protect alcohols in organic ...
In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest of the molecule's composition.
The tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group [1] (BOC group) is an acid-labile protecting group used in organic synthesis. The BOC group can be added to amines under aqueous conditions using di-tert-butyl dicarbonate in the presence of a base such as sodium hydroxide:
Di-tert-butyl dicarbonate is a reagent widely used in organic synthesis. [1] Since this compound can be regarded formally as the acid anhydride derived from a tert-butoxycarbonyl (Boc) group, it is commonly referred to as Boc anhydride. This pyrocarbonate reacts with amines to give N-tert-butoxycarbonyl or so-called Boc derivatives.
tert-Butyl hydroperoxide (tBuOOH) is the organic compound with the formula (CH 3) 3 COOH. It is one of the most widely used hydroperoxides in a variety of oxidation processes, like the Halcon process. [3] It is normally supplied as a 69–70% aqueous solution.
In organic chemistry, an alkyl group is an alkane missing one hydrogen. [1] The term alkyl is intentionally unspecific to include many possible substitutions. An acyclic alkyl has the general formula of −C n H 2n+1. A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H ...
The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...