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A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). [1] Examples are organolithium compounds and triethylborane.
An alternative industrial process for the preparation of very high-purity silane, suitable for use in the production of semiconductor-grade silicon, starts with metallurgical-grade silicon, hydrogen, and silicon tetrachloride and involves a complex series of redistribution reactions (producing byproducts that are recycled in the process) and ...
Pyrophoric liquids are liable to ignite after 5 minutes of coming in contact with air. Pyrophoric solids follow the same criteria as pyrophoric liquids. Self-heating substances, which differ from self-reactive substances in that they will only ignite in large quantities (kilograms) and after a long duration of time (hours or days).
Division 4.2: Spontaneously Combustible . Spontaneously combustible material is: Pyrophoric Material: A pyrophoric material is a liquid or solid that, even in small quantities and without an external ignition source, can ignite within five (5) minutes after coming in contact with air when tested according to the UN Manual of Tests and Criteria.
All chemicals that react vigorously with water or liberate toxic gas when in contact with water are recognized for their hazardous nature in the "Approved Supply List", [6] or the list of substances covered by the international legislation on major hazards [7] many of which are commonly used in manufacturing processes.
White phosphorus is rather acutely toxic, with a lethal dose of 50-100 mg (1 mg/kg body weight). Its mode of action is thought to involve its reducing properties. It is metabolized to phosphate, which is not toxic. [10] White phosphorus is used as a weapon because it is pyrophoric. For the same reasons, it is dangerous to handle.
Daily average mortgage rates on popular terms are rising as of Friday, December 20, 2024, with sharp moves higher for 30-year terms edging closer to 6.90% — an average 20 basis points higher ...
It is a colorless, pyrophoric liquid. [1] Unlike trimethylaluminium , TMG adopts a monomeric structure. [ 2 ] When examined in detail, the monomeric units are clearly linked by multiple weak Ga---C interactions, reminiscent of the situation for trimethylindium .