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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
The gemstone at the front of the Imperial State Crown. The Black Prince's Ruby is a large, irregular cabochon red spinel weighing 170 carats (34 g) set in the cross pattée above the Cullinan II diamond at the front of the Imperial State Crown of the United Kingdom. [1]
Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the "Timur ruby" in the British Crown Jewels, [11] and the "Côte de Bretagne", formerly from the French Crown jewels. [12] The Samarian Spinel is the largest known spinel in the world, weighing 500 carats (100 g). [13]
Samarian Spinel, the world's largest spinel; Menshikov Ruby, the world's second largest spinel set on top of the Great Imperial Crown of Russia; Timur Ruby, believed to be a ruby until 1851, hence its name; Black Prince's Ruby, the famous spinel mounted on the Imperial State Crown of the United Kingdom
Furthermore, most are very small, typically under 0.5 carats (100 mg) in weight. Their lusters range from vitreous to subadamantine, to almost metallic in the usually opaque melanite, which has been used to simulate black diamond. Some natural spinel is also deep black and could serve this same purpose.
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