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In particular, intermolecular hydrogen bonding is responsible for the high boiling point of water (100 °C) compared to the other group-16 hydrides that have much weaker hydrogen bonds. [11] Intramolecular hydrogen bonding is partly responsible for the secondary and tertiary structures of proteins and nucleic acids.
Avobenzone exists in the ground state as a mixture of the enol and keto forms, favoring the chelated enol. [4] This enol form is stabilized by intramolecular hydrogen-bonding within the β-diketone. [5]
The bond length, or the minimum separating distance between two atoms participating in bond formation, is determined by their repulsive and attractive forces along the internuclear direction. [3] As the two atoms get closer and closer, the positively charged nuclei repel, creating a force that attempts to push the atoms apart.
Intermolecular hydrogen bonding is responsible for the high boiling point of water (100 °C) compared to the other group 16 hydrides, which have little capability to hydrogen bond. Intramolecular hydrogen bonding is partly responsible for the secondary, tertiary, and quaternary structures of proteins and nucleic acids.
A hydrogen bond (H-bond), is a specific type of interaction that involves dipole–dipole attraction between a partially positive hydrogen atom and a highly electronegative, partially negative oxygen, nitrogen, sulfur, or fluorine atom (not covalently bound to said hydrogen atom). It is not a covalent bond, but instead is classified as a strong ...
2 O is sp 3 hybridized in which the 2s atomic orbital and the three 2p orbitals of oxygen are hybridized to form four new hybridized orbitals which then participate in bonding by overlapping with the hydrogen 1s orbitals. As such, the predicted shape and bond angle of sp 3 hybridization is tetrahedral and 109.5°. This is in open agreement with ...
Hydrogen bonds of the form A--H•••B occur when A and B are two highly electronegative atoms (usually N, O or F) such that A forms a highly polar covalent bond with H so that H has a partial positive charge, and B has a lone pair of electrons which is attracted to this partial positive charge and forms a hydrogen bond. [23]: 702 Hydrogen ...
Intramolecular hydrogen-bonding results in a very low basicity for 2-nitroaniline. Aside from its reduction to phenylenediamine, 2-nitroaniline undergoes other reactions anticipated for aromatic amines. It is protonated to give the anilinium salts.