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The mass number is different for each isotope of a given chemical element, and the difference between the mass number and the atomic number Z gives the number of neutrons (N) in the nucleus: N = A − Z. [2] The mass number is written either after the element name or as a superscript to the left of an element's symbol.
The chemists used an "atomic mass unit" (amu) scale such that the natural mixture of oxygen isotopes had an atomic mass 16, while the physicists assigned the same number 16 to only the atomic mass of the most common oxygen isotope (16 O, containing eight protons and eight neutrons).
The number of nucleons (both protons and neutrons) in the nucleus is the atom's mass number, and each isotope of a given element has a different mass number. For example, carbon-12 , carbon-13 , and carbon-14 are three isotopes of the element carbon with mass numbers 12, 13, and 14, respectively.
Nuclides with the same atomic mass number, but different atomic and neutron numbers, are called isobars. [8] The mass of a nucleus is always slightly less than the sum of its proton and neutron masses: the difference in mass represents the mass equivalent to nuclear binding energy, the energy which would need to be added to take the nucleus apart.
The difference between the neutron number and the atomic number is known as the neutron excess: D = N − Z = A − 2Z. Neutron number is not written explicitly in nuclide symbol notation, but can be inferred as it is the difference between the two left-hand numbers (atomic number and mass).
The atomic number can be used to uniquely identify ordinary chemical elements. In an ordinary uncharged atom, the atomic number is also equal to the number of electrons. For an ordinary atom which contains protons, neutrons and electrons, the sum of the atomic number Z and the neutron number N gives the atom's atomic mass number A.
A set of nuclides with equal proton number (atomic number), i.e., of the same chemical element but different neutron numbers, are called isotopes of the element. Particular nuclides are still often loosely called "isotopes", but the term "nuclide" is the correct one in general (i.e., when Z is not fixed).
In general, the mass number of a given nuclide differs in value slightly from its relative atomic mass, since the mass of each proton and neutron is not exactly 1 Da; since the electrons contribute a lesser share to the atomic mass as neutron number exceeds proton number; and because of the nuclear binding energy and electron binding energy ...