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Fullerenes had been predicted for some time, but only after their accidental synthesis in 1985 were they detected in nature [3] [4] and outer space. [5] [6] The discovery of fullerenes greatly expanded the number of known allotropes of carbon, which had previously been limited to graphite, diamond, and amorphous carbon such as soot and charcoal.
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Sir Harold Walter Kroto (born Harold Walter Krotoschiner; 7 October 1939 – 30 April 2016) was an English chemist.He shared the 1996 Nobel Prize in Chemistry with Robert Curl and Richard Smalley for their discovery of fullerenes.
Polyfullerene is a basic polymer of the C 60 monomer group, in which fullerene segments are connected via covalent bonds into a polymeric chain without side or bridging groups. They are called intrinsic polymeric fullerenes, or more often all C 60 polymers. Fullerene can be part of a polymer chain in many different ways.
Besides unfilled fullerenes, endohedral metallofullerenes develop with different cage sizes like La@C 60 or La@C 82 and as different isomer cages. Aside from the dominant presence of mono-metal cages, numerous di-metal endohedral complexes and the tri-metal carbide fullerenes like Sc 3 C 2 @C 80 were also isolated. In 1999 a discovery drew ...
Fullerene or C 60 is soccer-ball-shaped or I h with 12 pentagons and 20 hexagons. According to Euler's theorem these 12 pentagons are required for closure of the carbon network consisting of n hexagons and C 60 is the first stable fullerene because it is the smallest possible to obey this rule.
Heterofullerenes are classes of fullerenes, at least one carbon atom is replaced by another element. [ 1 ] [ 2 ] Based on spectroscopy , substitutions have been reported with boron ( borafullerenes ), [ 3 ] [ 4 ] nitrogen ( azafullerenes ), [ 5 ] [ 6 ] oxygen , [ 7 ] arsenic , germanium , [ 8 ] phosphorus , [ 9 ] silicon , [ 10 ] [ 11 ] iron ...
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