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Selenium dioxide imparts a red colour to glass. It is used in small quantities to counteract the colour due to iron impurities and so to create (apparently) colourless glass. In larger quantities, it gives a deep ruby red colour. Selenium dioxide is the active ingredient in some cold-bluing solutions.
Selenium is a nutrient that is naturally present in many foods, added to others and is also available as a dietary supplement in pill, powder and liquid form, explains Perri Halperin, a ...
The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells. Applications in electronics, once important, have been mostly replaced with silicon semiconductor devices. Selenium is still used in a few types of DC power surge protectors and one type of fluorescent quantum dot.
The ingredient is also used in body lotions to treat Tinea versicolor due to infection by a different species of Malassezia fungus. [12] Several clinical trials have assessed the use of selenium supplements in critically ill adults; however, the effectiveness and potential benefits of selenium supplementation in this context is not well ...
Selenium disulfide has been used in shampoo as an antidandruff agent, an inhibitor in polymer chemistry, a glass dye, and a reducing agent in fireworks. [6] Selenium trioxide may be synthesized by dehydrating selenic acid, H 2 SeO 4, which is itself produced by the oxidation of selenium dioxide with hydrogen peroxide: [8]
Oxidations involving selenium dioxide are often carried out with catalytic amounts of the selenium compound and in presence of a sacrificial catalyst or co-oxidant such as hydrogen peroxide. SeO 2-based oxidations sometimes afford carbonyl compounds such as ketones, [24] β-Pinene [25] and cyclohexanone oxidation to 1,2-cyclohexanedione. [26]
Selenium is toxic in high concentrations. As sodium selenite, the chronic toxic dose for human beings was described as about 2.4 to 3 milligrams of selenium per day. [7] In 2000, the US Institute of Medicine set the adult Tolerable upper intake levels (UL) for selenium from all sources - food, drinking water and dietary supplements - at 400 μg/day. [8]
Bluing solutions that operate in this manner will typically be labeled as containing selenous acid or selenium dioxide. [2] [3] It has also been investigated for use in the treatment of colon cancer. [4]
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