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The monohydrate and dihydrate can be distinguished by the shape of the respective crystals. Calcium oxalate dihydrate crystals are octahedral. A large portion of the crystals in a urine sediment will have this type of morphology, as they can grow at any pH and naturally occur in normal urine.
Weddellite, or calcium oxalate dihydrate, crystallises in a tetragonal system: the classic crystal shape is the eight-face bipyramid. Using bright field microscopy, the weddellite crystals are recognised easily by their shape, reminiscent of a postal envelope. More complex shapes of weddellite are possible; the dumbbell shape is not rare and ...
Two types naturally occur, calcium oxalate monohydrate, or whewellite (CaC 2 O 4 ·H 2 O), and calcium oxalate dihydrate, or weddellite (CaC 2 O 4 ·2H 2 O). Their appearance can be rough, smooth, spiculated (needle-like), or jackstone. Calcium oxalate stones form more readily in animals with hypercalcaemia, which can be caused by Addison's ...
Rhubarb leaves contain about 0.5% oxalic acid, and jack-in-the-pulpit (Arisaema triphyllum) contains calcium oxalate crystals. Similarly, the Virginia creeper, a common decorative vine, produces oxalic acid in its berries as well as oxalate crystals in the sap, in the form of raphides. Bacteria produce oxalates from oxidation of carbohydrates. [16]
Oxalate (systematic IUPAC name: ethanedioate) is an anion with the chemical formula C 2 O 2− 4.This dianion is colorless. It occurs naturally, including in some foods. It forms a variety of salts, for example sodium oxalate (Na 2 C 2 O 4), and several esters such as dimethyl oxalate ((CH 3) 2 C 2 O 4).
Raphides in Epipremnum Devil's ivy (600× magnification). Raphides (/ ˈ r æ f ɪ d i z / RAF-id-eez; singular raphide / ˈ r eɪ f aɪ d / RAY-fyde or raphis) are needle-shaped crystals of calcium oxalate monohydrate (prismatic monoclinic crystals) or calcium carbonate as aragonite (dipyramidal orthorhombic crystals), found in more than 200 families of plants.
Whewellite / ˈ h juː ə l aɪ t / is a mineral, hydrated calcium oxalate, formula Ca C 2 O 4 ·H 2 O. [6] Because of its organic content it is thought to have an indirect biological origin; this hypothesis is supported by its presence in coal and sedimentary nodules. However, it has also been found in hydrothermal deposits where a biological ...
They are almost always composed of calcium oxalate dihydrate and consist of a dense central core and radiating spicules. They are typically light brown with dark patches and are usually formed in the urinary bladder and rarely in the upper urinary tract.