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Titanium hydride normally refers to the inorganic compound TiH 2 and related nonstoichiometric materials. [1] [2] It is commercially available as a stable grey/black powder, which is used as an additive in the production of Alnico sintered magnets, in the sintering of powdered metals, the production of metal foam, the production of powdered titanium metal and in pyrotechnics.
In the direct powder rolling (DPR) process BE powder is used to produce sheet and plate and composite multilayered sheet and plates. Sheets between 1.27 and 2.54 mm and 50 to 99+% dense of single layer CP titanium, Ti Grade 5, TiAl (Ti-48Al-2Cr-2Nb) and composite Ti/Grade 5/Ti and Grade 5/TiAl/Grade 5 have been produced by DPR and sintering.
Metal hydride-oxidizer mixtures replace the metal with its corresponding hydride. They are generally safer to handle than the corresponding metal-oxidizer compositions. During burning they also release hydrogen, which can act as a secondary fuel. Zirconium hydride, titanium hydride, and boron hydride are commonly used.
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Titanium(IV) hydride was first produced in 1963 by the photodissociation of mixtures of TiCl 4 and H 2, followed by immediate mass spectrometry. [1] Rapid analysis was required as titanium(IV) hydride is extremely unstable. Computational analysis of TiH 4 has given a theoretical bond dissociation energy (relative to M+4H) of 132 kcal/mole. [2]
Titanium(II) hydride – together with potassium perchlorate it is used in some igniters; Zirconium(II) hydride – together with potassium perchlorate it is used in some igniters; Aluminum hydride – unstable for storage (decomposes easily with humidity) and reacts dangerously in contact with water; Decaborane – experimented with for some ...
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