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The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. [1] For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase : [2]
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
The molar concentration is defined as the amount of a constituent (in moles) divided by the volume of the mixture : =. The SI unit is mol/m 3. However, more commonly the unit mol/L (= mol/dm 3) is used.
Normality is defined as the number of gram or mole equivalents of solute present in one liter of solution.The SI unit of normality is equivalents per liter (Eq/L). = where N is normality, m sol is the mass of solute in grams, EW sol is the equivalent weight of solute, and V soln is the volume of the entire solution in liters.
An apparent molar quantity can be similarly defined for the component identified as solvent ~ . Some authors have reported apparent molar volumes of both (liquid) components of the same solution. [1] [2] This procedure can be extended to ternary and multicomponent mixtures.
The mole is not a true metric (i.e. measuring) unit, rather it is a parametric unit, and amount of substance is a parametric base quantity [26] the SI defines numbers of entities as quantities of dimension one, and thus ignores the ontological distinction between entities and units of continuous quantities [27]
of SI base units mole per cubic metre: mol/m 3: molarity, amount of substance concentration: m −3 ⋅mol cubic metre per mole: m 3 /mol molar volume: m 3 ⋅mol −1: joule per kelvin mole: J/(K⋅mol) molar heat capacity, molar entropy m 2 ⋅kg⋅s −2 ⋅K −1 ⋅mol −1: joule per mole: J/mol molar energy: m 2 ⋅kg⋅s −2 ⋅mol − ...