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Beryllium fluoride is the inorganic compound with the formula Be F 2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF 2 is highly soluble in water.
The structure is tetragonal and puts metal atoms in octahedral coordination. Beryllium difluoride is different from the other difluorides. In general, beryllium has a tendency to bond covalently, much more so than the other alkaline earths and its fluoride is partially covalent (although still more ionic than its other halides).
Tetrafluoroberyllate or orthofluoroberyllate is an anion with the chemical formula [Be F 4] 2−. It contains beryllium and fluorine. This fluoroanion has a tetrahedral shape, with the four fluorine atoms surrounding a central beryllium atom. It has the same size, charge, and outer electron structure as sulfate S O 2− 4. Therefore, many ...
Structure of beryllium fluoride (BeF 2), a compound with a linear geometry at the beryllium atom. The linear molecular geometry describes the geometry around a central atom bonded to two other atoms (or ligands) placed at a bond angle of 180°.
Beryllium hydroxide created using either the sinter or melt method is then converted into beryllium fluoride or beryllium chloride. To form the fluoride, aqueous ammonium hydrogen fluoride is added to beryllium hydroxide to yield a precipitate of ammonium tetrafluoroberyllate, which is heated to 1,000 °C (1,830 °F) to form beryllium fluoride. [9]
Lewis bases, such as the alkali fluorides, will donate fluoride ions to the beryllium, breaking the glassy bonds which increase viscosity. In FLiBe, beryllium fluoride is able to sequester two fluoride ions from two lithium fluorides in a liquid state, converting it into the tetrafluoroberyllate ion [BeF 4] 2−. [7]
Difluorides are chemical compounds with two fluorine atoms per molecule (or per formula unit). Metal difluorides are all ionic. Despite being highly ionic, the alkaline earth metal difluorides generally have extremely high lattice stability and are thus insoluble in water. The exception is beryllium difluoride.
Beryllium bromide – BeBr 2 [108] Beryllium carbonate – BeCO 3 [109] Beryllium chloride – BeCl 2 [110] Beryllium fluoride – BeF 2 [111] Beryllium hydride – BeH 2 [112] Beryllium hydroxide – Be(OH) 2 [113] Beryllium iodide – BeI 2 [114] Beryllium nitrate – Be(NO 3) 2 [115] Beryllium nitride – Be 3 N 2 [116] [117] Beryllium oxide ...