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Rigid boundary – not allowing exchange of work: A mechanically isolated system One example is fluid being compressed by a piston in a cylinder. Another example of a closed system is a bomb calorimeter , a type of constant-volume calorimeter used in measuring the heat of combustion of a particular reaction.
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.
In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The specific volume, an intensive property, is the system's volume per unit mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature.
In thermodynamics, the specific volume of a substance (symbol: ν, nu) is the quotient of the substance's volume (V) to its mass (m): = It is a mass-specific intrinsic property of the substance. It is the reciprocal of density ρ and it is also related to the molar volume and molar mass:
The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system. However, the second law of thermodynamics is not a defining relation for the entropy.
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation.
According to the second law of thermodynamics, a system assumes a configuration of maximum entropy at thermodynamic equilibrium. We seek a probability distribution of states ρ i {\displaystyle \rho _{i}} that maximizes the discrete Gibbs entropy S = − k B ∑ i ρ i ln ρ i {\displaystyle S=-k_{\text{B}}\sum _{i}\rho _{i}\ln \rho _{i ...
At present, there is no single equation of state that accurately predicts the properties of all substances under all conditions. An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures.